Short answer: not that breaker, no.
Long answer: you need to contact Siemens (not a Siemens dealer, not an orange apron, Siemens. And you need to ask them the following question:
I have a Siemens CTL panel. Does Siemens now authorize use of non-CTL breakers in that panel?
The reason you need to ask is this is a rapidly changing area, as manufacturers and UL figure out what to do about the repeal of CTL limitations. I understand Eaton has gone for the jugular, got UL to approve non-CTL breakers in all legacy Eaton
panels, and plans to stop making CTL breakers. Siemens may be doing the same.
However, what I would really do.
A subpanel, yes - but in the garage. This wraps up a whole bunch of problems nicely, with a bow.
- Lets you pay $2/foot for wire instead of gold-rush prices for copper (the market has gone insane).
- Brings 90A to the garage - plenty for charging two EVs. While also being able to support other loads, such as the two 120V circuits you feed out of this panel instead of the main panel.
- Provides a local disconnect. Which allows hardwiring the EVSE, which saves money on sockets and allows more total power (60A: OK).
- hardwiring also avoids a very stupid "double GFCI" situation in NEC 2020 territory.
Now how do we get two EVs on 90 amps? Good question. Share2 technology, which is safety-rated and UL approved. EV's already negotiate charge rates with the wall unit (the thing you call a "charger", actually an EVSE). With Share2, the EVSE's simply coordinate.
How do we get 90A for $2/ft? By shattering some preconceptions about aluminum. Science proved that aluminum is only bad when you attach it to terminals not rated for aluminum. Other science not related to aluminum also proved terminal screw torques are really important, even on small connections. That's what went wrong in the 70's on small branch circuit wiring. Heavy feeder has always been reliable. Heck the large lugs are made of aluminum!
So we use #2 aluminum for 90A, which happens to be in a pricing "sweet spot" due to its widespread use. Or 1/0 aluminum for 120A if you want to go deluxe.
The subpanel also provides a suitable coupler to step from aluminum to copper for the short final run to the EVSE. Most EVSE terminals are not rated for aluminum, and we won't repeat That 70's mistake.
And yes, your breaker can go in a Siemens subpanel.
For the subpanel I'd go nice and large. Spaces are cheap, and - well, I hardly need to explain to you the cost of running out of spaces because you chintzed out.
As for GFCI, the EVSE already has a superb, first-rate GFCI in it, with a special feature: a recloser. It will wait and then reset its own GFCI several times to see if the fault has cleared (which it usually does). That is important so you don't get stranded with no battery charge. A second GFCI will interfere with this, by also tripping, leaving the EVSE dead as a stone. Don't put GFCIs on GFCIs.