@ecnerwal gave a workable solution, but before you go ahead and attempt to remove the valve, you might try a direct assault on the valve while it's still in place with the goal of getting it to operate.
I've had luck getting a valve to un-stick by applying heat and vibration while repeatedly forcing the valve handle back and forth.
For heat, protect the area behind the pipes with something fireproof, then hit the valve with a torch. Go as hot as you dare, with consideration for seals.
For vibration, nothing beats an air hammer with a flat-faced impact tool. It could beat on one of the flats of one of the nuts and send waves of vibration through the valve. Vibrate while trying to open/close the valve, and it may eventually start moving.
And at least if it doesn't work, everyone in the house will know you're working on it!