Summary of non-toxic finishing products for wooden bowls and wood cutting boards:
Mineral oil: derived from petroleum, it is colorless, odorless, tasteless and entirely inert. Simple to apply, low water resistance, frequent reapplication. Highly processed variants are food safe and labelled as such. Do not confuse with mineral oils used as machine oil.
Beeswax: The work of the honey bee, extracted from frames in a bee hive. Best applied when heated. Ask your local beekeeper.
Shellac. A secretion from the lac bug. A film-forming finish, which is easy to wipe and clean with a moist cloth. Use high-purity denatured alcohol as a solvent, as it leaves no toxic residue.
Raw linseed oil: Pressed from flax seeds. Very long curing time, good looks, low water-resistance, frequent reapplication. FOr shorter drying time use polymerized linseed oil which is still food safe, but not "boiled" linseed oil. Rags may self-combust.
Pure tung oil:, from the nut of the china wood tree. Difficult to apply, requires many coats, good water-resistance.
Walnut oil: Pressed from the nuts of the walnut tree. Dries and won't go rancid. Easy to apply, frequent reapplication.
Carnauba wax: Derived from the Brazilian palm tree. Straight on woodenware as a light protective coating or a topcoat polish.
The above is abridged, reordered to my preference, and mildly edited, from https://www.newhampshirebowlandboard.com/blogs/blog/13612445-food-safe-finishes-for-wooden-bowls-and-wood-cutting-boards
More on the variants of linseed oils:
- Raw Linseed Oil is the purest, most natural form of the oil. It is the kind used in nutritional supplements
- Polymerized Linseed Oil is created by heating raw linseed oil in the absence of oxygen to about 300°C (572°F) over the course of several days.
- Boiled Linseed Oil has drying agents (either petroleum-based or heavy metals) added. It is the least food-safe of the three.
Ref: https://vermontwoodsstudios.com/blog/raw-vs-boiled-vs-polymerized-linseed-oil/
More on tung vs linseed oil: https://woodworkingtoolkit.com/tung-oil-vs-linseed-oil/
Self-Combustion of Oily Rags
The reader should be cautioned about the storage of oily rags:
The entire combustion process of the samples includes 4 typical stages: low-temperature oxidation stage, thermal decomposition stage, combustion stage, and after-combustion stage. The activation energy of the low-temperature oxidation stage reached as low as 33.13 kJ/mol, indicating that the vegetable oil is extremely prone to self-oxidation even when the temperature <200 °C. And the self-ignition tendency was in the order linseed oil > perilla seed oil > safflower seed oil
The continuous oxidation and self-heating of vegetable oils in the air can result in the occurrence of fire due to thermal runaway via heat accumulation. This is especially true when the unsaturated vegetable oil is immersed in a carrier such as cotton cloth or fiber, as the much larger contact area between O2 and oil results in an oxidation rate and thereby increases the risk of fire. If there is sufficient accumulation in the carrier, the heat released by the reaction can easily accumulate due to the overlay effect of the accumulation. Once the ignition temperature is reached, the oil will burn in the presence of O2.
https://www.sciencedirect.com/science/article/abs/pii/S0360544221031364