Edit: All wires discussed here are aluminum. Nevermind my previous typos.
This is you not using the calculator properly. Most novices make the same mistake.
First, DO NOT use an amp value of "breaker trip". Use the actual calculated load, e.g. if the load calculates out to 12240 VA or 51 amps, then use 51 amps. Regardless, you should never use more than 80% of breaker trip, because it's illegal to plan to load the panel that heavily. Consumer tier panels are only rated for 80% continuous load.
Second, 3% is only a wire salesman's suggestion. It's not in Code anywhere except in Canada, and there, they want 3% but at the above rule - actual load and never more than 80% of breaker trip.
So, when we calculate it on that basis - aluminum, 235', 240V, well over 3%, and 80 amps -- we get 1/0 aluminum at 3.26%. And that's just fine.
Or 1 AWG aluminum at 3.80% which is fine too, but since you're worried about it, go 1/0.
So, 1/0 aluminum is your best play. It fits the lugs natively, no fuss.
Remember feeders must be 4 wires.
Since you enlarged the beyond the minimum mandatory 1 AWG AL, you must enlarge ground in proportion (same number of AWG sizes) per 250.122(B). Minimum 100A feeder ground is 6 AWG, so you need
- with 1/0 hots: 5 AWG ground, doesn't exist so you'll have to use 4 AWG.
- With 3/0 hots: 3 AWG ground, again that probably means 2 AWG.
But yes, you can use Polaris to step down wires like that. It's just better avoided with brain power. Note that you wouldn't even need to use 1/0 for the pigtail since #1 would suffice.