Power Sharing
Yes, there is technology for this, but you'll need to evolve past the flimsy charge cords.
Tesla used to call it "Power Sharing" and now calls it "Group Power Management". Several brands support it including Wallbox Pulsar Plus. Multiple EVSEs are placed in a group, and the group is programmed for a number of amps it can share. In your case, 16 amps.
The stations coordinate - if only one car is charging, it gets 16A. When a second car plugs in, they share 8A. When one car finishes, the other car gets the full 16A. This very effectively balances charging among multiple cars, wasting no capacity.
Now you need to shop carefully. A few EVSE makers built things lazy, and have no way to reduce a car's allocation below 6 amps. Thus, every station gets assigned 6 amps whether it is using it or not. With those stations, with only one car plugged in, that car would be limited to 10 amps.
We are talking about hardwired stations here. This tech is not compatible with sockets for a variety of reasons, like no auxiliary pins in the socket to share a capacity signal.
Smart plugs
I'm not a fan, but I know many people get hung up on sockets. In that case, you use general smart-home stuff to turn on one of the sockets, wait until either it stops drawing current or 1 hour, whichever comes first, and then switch it off and switch on the other socket. So you'd be switching every hour until 1 car is full, then switching to the other car and retrying the first car once an hour.
Give one car 16A. Give the other car EVEMS
This is one of my favorites. On a panel with limited capacity on the standard service load calculation, and the need for multiple EV stations, you set up 2 stations.
Station #1, the "little" station, is a fixed load that uses the remaining headroom on the load calculation. E.g. 16A.
Station #2 uses EVEMS. It is taking advantage of the fact that the service load calculation must assume a probable worst case scenario of many appliances being used at once, but that's not actually true 99.99% of the time. So it has a monitor on the supply wires, and it is dynamically adjusting EV charge rate to use the capacity headroom that is in the house right now. Because of this, it can take as much as the whole service, and it is actually the more powerful of the 2 stations.
You then make competent personal choices to plug the more hungry car into station #2.