IMO replacing a properly installed tandem breaker with a single breaker plus a wire nut inside the breaker panel purely for aesthetic/elegance reasons is not worth pursuing. You aren't really reducing crowding and you're adding complexity.
I've been contemplating doing something similar to what you suggest, but in a full panel combining 8 circuits into two. Most of them are not lighting, they serve one socket that does nothing but charge phones, or perhaps once-upon-a-time served a window A/C (before central was installed).
My approach would be to install a splice box near the breaker panel, high up on the basement wall so there would be plenty of cable to work with, and to use 5-way lever nuts as neatly as possible inside that box, and connect it to the breaker panel with a conduit and four wires.
This would meaningfully reduce crowding in the breaker panel and regain breaker spaces.
The eight circuits use a mixture of 12 and 14 ga wire, so the two breakers serving them would have to be 15A and in one place where there is a 20A outlet I'd have to replace it with a 15.