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When applying thinset, put it on in a flat coat first,, and lay it on thick, pressing it against the wall or floor. THEN go back at an angle and notch it, removing excess. This makes sure the thinset has good contact with the wall over the whole area and will bond well. Laying it on at an angle, so it's notched in one pass, doesn't spread the thinset over ...

I've never done or heard of this, but most of my small tile work has been with presheeted tiles I did read about a mosaic system where the layout was done face up and a mesh was attached, and the tile was thin-setted and afterwards grouted. I've also seen a TOH segment where the mosaic was attached to a thin cement board (1/4"), grouted and then the whole ...

Generally glass bonding is done with a special adhesive that is UV cured. I'm uncertain as much as far as the cost for it. I have always used silicone to bond glass, it's what my family business uses to assemble/repair fish tanks. The silicone would also work perfect for you in place of grout.